~ Physical Chemistry Resources ~
TOPICS.
Bohr Atom
Bohr Atom – The so-called Bohr atom is an attempt by Bohr to
explain the structure of an atom and the role played by the electrons.
Unfortunately, it is incomplete and only partly achieves its intent. In the
simple Bohr atom the electrons are considered to spin around the positively
charged nucleus where the attractive electrostatic force between the positive
nucleus and the negative electron is balanced by the centrifugal force of the
rotating electron. This portrayal of the atomic mechanism is true as far as it
goes but does not explain the different orbits that correspond to different
energy levels of the electron orbiting the nucleus. De Broglie
considered the electron to have wave properties where the locus of the electron
orbiting the nucleus was an integral number wavelengths
that allowed the electron to act as a standing wave round the nucleus. Thus,
the electron can have different ‘orbits’ around the nucleus where the locus of
the ‘orbit’ is an exact number of wavelengths and each orbit corresponds to a
specific energy. Consequently, the energy of the electron in each of its
possible ‘orbits’ is defined by its wavelength. The latter description of the
orbiting electron is now accepted but Bohr’s concept was important in that it
initiated a understanding of the orbiting electron
although did not give a complete understanding of the process.